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I would like to use V120:Slim cameras and I want to use OptiHub　for synchronizing with external devices.

In the OptiHub User Manual, it is wrote Trigger Rate max is 100Hz.

Can I use OptiHub for the OptiSync in V120:Slim camera systems?

Most definately!

The OptiHub can handle Trigger frequencies of 8hz to 120hz. As V120:Slims don't support OptiSync (synchronization signal over USB from the OptiHub) you will need to use wired sync (RCA cables between cameras). Plug the external sync cable into the external sync in on the OptiHub, then plug an RCA cable into the OptiSync out of the hub, and connect it to the sync in on the first camera, and continue the wired sync as usual.